
At a Glance
Four numbers behind the Montreal Protocol’s record.
99%+ phased out
Over 99% of controlled ozone-depleting substances have been phased out worldwide.
1 Dec 2025 closure
The earliest Antarctic ozone-hole closure since 2019, the fifth-smallest since 1992.
2028 freeze, 2047 cut
India’s HFC baseline freezes in 2028, reaching an 85% cumulative cut by 2047.
16 September
Both the Montreal Protocol’s signing date and World Ozone Day.
In this lesson
Timeline: 1987 to the 2025 Closure
From signing to this year’s record closure
- 1987: the Montreal Protocol is signed by 46 countries, on 16 September 1987, to phase out ozone-depleting substances.
- 1992: full controls take effect. Ozone-hole recovery tracking begins from this year.
- 2021: India ratifies the Kigali Amendment on 21 September 2021, extending the Protocol to cover HFCs.
- 2025: the Antarctic ozone hole closes on 1 December, its earliest closure since 2019, and the fifth-smallest hole since 1992.
True or False: The Montreal Protocol was signed in 1987 by 46 countries.
The Montreal Protocol and Its Progress
The Protocol’s record, and the recovery timeline
- The Montreal Protocol was signed on 16 September 1987, to phase out ozone-depleting substances like CFCs.
- Over 99% of controlled ozone-depleting substances have been phased out worldwide since then.
- The 2025 Antarctic ozone hole was the fifth-smallest since 1992. It closed on 1 December, the earliest closure since 2019.
- The ozone layer is projected to fully recover to 1980 levels: Antarctica by 2066, the Arctic by 2045, and the rest of the world by 2040.
The chemistry: how CFCs destroy ozone
- The culprits: CFCs, HCFCs, and halons are the main ozone-depleting substances. CFCs were once common in refrigerants and aerosol sprays; halons in fire extinguishers.
- These compounds are chemically inert in the lower atmosphere. That is exactly why they drift, unbroken, up into the stratosphere over years.
- Once in the stratosphere, intense UV radiation breaks these molecules apart, releasing free chlorine and bromine radicals.
- A chlorine radical rips an oxygen atom off an ozone molecule, forming chlorine monoxide and leaving ordinary oxygen. The chlorine monoxide then reacts with a second ozone molecule, releasing the original chlorine atom again.
- Because the chlorine atom comes out unchanged, it repeats this cycle. A single chlorine atom can destroy tens of thousands of ozone molecules before it is finally removed from the stratosphere.
Remember: a thinner ozone layer lets more UV-B radiation reach the ground. That raises skin cancer and cataract risk, and damages crops and phytoplankton, the base of the marine food chain.
True or False: A chlorine radical is consumed and destroyed after it breaks apart just one ozone molecule.
True or False: A thinner ozone layer lets more UV-B radiation reach the Earth’s surface, raising skin cancer and cataract risk.
True or False: Over 99% of controlled ozone-depleting substances have been phased out worldwide since the Montreal Protocol.
The Kigali Amendment and India’s Timeline
HFCs, and India’s own schedule
- The Kigali Amendment (2016) added HFCs to the Protocol’s coverage. HFCs don’t harm the ozone layer, but they are powerful greenhouse gases.
- India ratified the Kigali Amendment on 21 September 2021.
- India’s HFC baseline is the average production and consumption across 2024, 2025, and 2026. A freeze at that level begins in 2028.
- After the freeze: 10% cut by 2032, 20% by 2037, 30% by 2042, and a cumulative 85% by 2047.
True or False: HFCs, added to the Montreal Protocol by the Kigali Amendment, directly damage the ozone layer.
Why the Protocol Worked
A treaty built to adapt, and India’s long runway
- Ozone protection and climate protection now run through the same treaty. Kigali turned a pure ozone agreement into a climate one too, since CFC replacements turned out to be potent greenhouse gases.
- The Protocol succeeded partly because it was built to be strengthened. Later amendments, like Kigali, could add new substances without renegotiating the whole treaty.
- India’s phase-down math gives industry a long runway. The baseline is set now, the freeze starts in 2028, and the final 85% cut isn’t due until 2047.
- For the mitigation-adaptation framework and the Kyoto Protocol angle, see EnvEco0002.
True or False: Ozone (O3) is concentrated in the stratosphere because that’s where its three-atom structure forms.
Think it through: why did Kigali turn Montreal into a climate treaty too?
The chemicals that replaced ozone-depleting CFCs, like HFCs, turned out to be safe for the ozone layer but were powerful greenhouse gases. Adding HFC controls under Kigali meant the same treaty now also addresses climate change, not just ozone depletion.
Previous Year Questions
Three traps examiners keep returning to: what HFCs are actually used for, where the ozone hole forms, and which treaty controls what.
- CSP 2023Asked how many of aerosols, foam agents, fire retardants, and lubricants use HFCs. The answer is three: aerosols, foam agents, and fire retardants. HFCs are not typically used in lubricants.
- CAPF (ACs) 2026Asked where the ozone hole is prominently observed: the Antarctic region. Extreme cold there in the stratospheric winter creates polar stratospheric clouds, which speed up ozone-destroying reactions each spring.
- NDA-NA (II) 2016Tested whether ozone’s tri-atomic structure and its concentration in the stratosphere are related. Both facts are true, but one does not explain the other — the structure comes from how ozone forms chemically, not from where it sits.
- CSP 2015Asked which agreement controls and phases out ozone-depleting substances: the Montreal Protocol. Kyoto and Paris instead target greenhouse gas emissions broadly.
Current Affairs
32nd World Ozone Day, 2026
- India marked the 32nd World Ozone Day in Mumbai on 16 September 2026, themed “Global Action for a Cooler Planet.”
- The Environment Ministry said India has exceeded its Montreal Protocol commitments without slowing its own development.
- India’s Net Zero Portal and NAPCC Dashboard were both launched on this same World Ozone Day.
- 248 ITIs were adopted by 12 refrigeration and air-conditioning manufacturers, to align technician training with industry needs. (Source: PIB)
True or False: India’s Net Zero Portal and NAPCC Dashboard were both launched on the 32nd World Ozone Day in 2026.
True or False: Under Kigali, India’s HFC production and consumption freeze begins in 2028.
Quick Q&A
When is World Ozone Day, and when was the Montreal Protocol signed?
Both fall on 16 September. The International Day for the Preservation of the Ozone Layer is not 16 November, a common trap.
Why can a single chlorine atom destroy tens of thousands of ozone molecules?
The chlorine atom comes out of each reaction unchanged, so it repeats the destructive cycle until other reactions finally remove it.
Do HFCs damage the ozone layer?
No. They are safe for ozone, but are powerful greenhouse gases, which is why the Kigali Amendment added them to the Protocol.
What is India’s final HFC reduction target, and by when?
An 85% cumulative cut by 2047, after a freeze beginning in 2028.
Why does the ozone hole form specifically over Antarctica?
Extreme cold there creates polar stratospheric clouds in winter, which speed up ozone-destroying reactions each spring.
🎲 Practice: Ozone Layer Protection
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